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   54
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    Tsuber, Viktoriia Yuriivna.
    Medical Chemistry : textbook [for foreign students seeking higher education with a master's degree, majoring in specialties 221 ''Dentistry'', 222 ''Medicine'' in higher education institutions of the Ministry of Health of Ukraine] / V. Y. Tsuber, A. A. Kotvytska, K. V. Tykhonovych ; ed. V. Y. Tsuber. - K. : Medicine Publishing, 2022. - 391 p. : graph., scheme, il. ; 22 cm. - На англ. мові. - Index words: p. 386-391. - ISBN 978-617-505-895-4 : 400.00 грн.
Переклад назви: Медична хімія: підручник / В. Ю. Цубер, А. А. Котвицька, К. В. Тихонович

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54:61(075.8)

Рубрики: ХІМІЯ(АНГЛ)--Підручник

МЕДИЦИНА

Кл.слова (ненормовані):
підручники
Анотація: Contents Preface..........................9 CHAPTER 1. Chemical thermodynamics................ 11 Thermodynamic system.............. 11 Thermodynamic parameters and thermodynamic processes..................... 13 Internal energy..................... 14 Enthalpy...................... 15 Standard enthalpy change............. 17 The Hess' law.................... 18 Calorimetry.................... 21 Energy values of nutrients.............22 The First Law of Thermodynamics .............23 Entropy....................... 24 Second Law of Thermodynamics .............29 Free energy ....................32 Spontaneous processes..................32 Macroergic compounds in the organism......... 36 CHAPTER 2. Chemical kinetics................. 42 Rate of chemical reaction................42 Factors that affect reaction rate.............44 Effect of concentrations of substances on reaction rate. Law of mass action....................46 Molecularity of reactions .................48 Reaction order .....................50 Effect of temperature on reaction rate............ 51 Recap of collision theory of reaction rate.......... 57 Complex reactions..................... 58 Catalysis......................... 65 Properties of catalysts................. 65 Important concepts of catalysis.............. 66 Catalysis by phase: heterogeneous and homogeneous catalysts....................... 68 Catalysis by chemical interaction: acid-base and redox catalysts....................... 71 Mechanism of catalysis................. 72 Theories of catalysis................... 73 Enzymes......................... 75 Properties of enzymes ................75 Measuring enzyme activity............... 76 Classification of enzymes................. 77 Properties of the active site..............77 Kinetics and mechanism of enzyme activity......... 78 Factors affecting velocity of enzymic reactions........ 81 Inhibition of enzyme activity.............. 82 Regulation of enzyme activity............. 84 Medical enzymology.................. 86 CHAPTER 3. Chemical equilibrium. Heterogeneous equilibriums in the organism ......................91 Chemical equilibrium....................91 Kinetics of chemical equilibrium.............. 91 Factors affecting chemical equilibrium. Le Chatelier's principle...................... 93 Thermodynamics of chemical equilibrium......... 98 Solubility product. Heterogeneous equilibriums in the organism... 100 Solubility product.................. 101 Heterogeneous equilibriums in the organism......... 105 Formation and remodeling of bone tissue........ 105 Formation of kidney stones............ 106 CHAPTER 4. Biogenic elements................ 109 Classification of biogenic elements by the amount in the organism.................. 109 Classification of biogenic elements by the electron structure of the valence shell.................. 110 ^lacroelements...................... 112 Macroelements of the s-block.............. 112 Macroelements of the p-block............. 118 Microelements...................... 133 Microelements of the s-block............... 133 Microelements of the p-block............... 134 Microelements of the d-b\ock.............. 135 CHAPTER 5. Coordination complexes ................ 148 Structure of coordination complexes.......... 148 Coordination number and denticity of ligands....... 149 Donor-acceptor mechanism of bond formation........ 150 Isomerism of coordination complexes........... 151 Classification of coordination complexes......... 151 Nomenclature of coordination complexes .......... 152 Stability constant of coordination complexes......... 153 Chelate complexes................... 154 Coordination complexes in the organism......... 159 CHAPTER 6. Solutions. Solubility. Composition of solutions....... 168 Solutions...................... 168 Classification of solutions............... 168 Solubility...................... 169 Polarity...................... 170 Mechanism of dissolution.............. 171 Solubility of gases in liquids.............. 173 Transport of gases in blood............ 176 Nernst distribution law................ 177 Composition of solutions.................. 179 Mass fraction..................... 179 Mole fraction..................... 182 Molarity....................... 182 Normality..................... 185 Molality..................... 189 Measurements of concentration of solutions. Titrimetric analysis......................... 190 Methods of titrimetric analysis by chemical reaction...... 193 Acid-base titration................. 193 Complexonometric titration.............. 197 Redox titration................... 198 Precipitation titration.................. 200 Methods of titrimetric analysis by technique ......... 201 Colligative properties of solutions.............. 201 Vapor pressure depression.............. 202 Equilibrium vapor pressure............. 202 Raoult'sLaw...................203 Boiling point elevation................ 204 Freezing point depression.............. 205 Osmosis..................... 207 Osmotic pressure................ 207 Osmolarity and osmolality..............209 Isotonic, hypotonic, and hypertonic solutions....... 209 Plasmolysis and hemolysis..............210 Solutions isotonic to blood............. 211 The osmotic pressure of blood. Osmoregulation....212 CHAPTER 7. Acids and bases. Buffer solutions ............. 216 Electrolytes .....................216 Acids and bases..................... 217 Ion theory (Arrhenius definition)............ 217 Proton theory (Bransted-Lowry definition)...... 219 Electron theory (Lewis) ..............219 Dissociation of water ..................219 Salt hydrolysis....................222 Hydrolysis constant.................. 223 Degree of salt hydrolysis................ 224 Buffer solutions..................... 225 Types of buffer solutions................ 225 Mechanism of buffering................. 226 Buffer capacity................... 229 pH of buffer solutions. Henderson—Hasselbalch equation... 230 Acid-base homeostasis................... 232 Buffer systems of blood............... 233 Disorders of acid-base homeostasis............ 235 CHAPTER 8. Electrode processes................. 240 Electrode potential................... 240Galvanic cell. Electromotive force............. 246 Potentiometry.................... 248 Diffusion potential...................252 Membrane potential................. 252 Redox systems. Redox potentials............... 253 Redox reactions in the organism. Biological oxidation......256 CHAPTER 9. Surface phenomena. Adsorption. Chromatography...... 263 Surface phenomena.................. 263 Adsorption ......................264 Surface phenomena at liquid-gas phase interfaces. Surface tension................... 266 Surface-active compounds................ 268 Surface phenomena at liquid-liquid phase interface. Emulsions..................... 273 Surface phenomena at immobile phase interfaces..... 276 Molecular adsorption..................279 Chromatography ...................287 Methods of Chromatography by aggregate state of phases ......................287 Methods of Chromatography by type of interaction..... 290 Methods of Chromatography by technique.......... 293 CHAPTER 10. Disperse systems. Colloidal solutions......... 300 Disperse systems................... 300 Colloidal solutions ...................302 Purification of colloidal solutions ........... 304 Preparation of colloidal solutions............ 308 Structure of colloidal particles .............313 Molecular-kinetic properties of colloidal solutions...... 315 Electrokinetic properties of colloidal solutions ......318 Optical properties of colloidal solutions........... 322 Stability of colloidal solutions.............. 325 Coagulation of lyophobic colloidal solutions .........326 Colloidal protection................. 331 CHAPTER 11. High-molecular compounds and their solutions....... 335 Classification of polymers.............. 335 Synthesis of polymers.................. 342 Biopolymers.................... 344 Proteins..................... 345 Polysaccharides.................. 352 Nucleic acids................... 358 Isoelectric point (pi) of proteins............. 364 Properties of polymer solutions............... 371 Viscosity of polymer solutions.............. 372 Dissolution of polymers. Swelling........... 377 Gels........................ 380 Index words......................... 386
Дод.точки доступу:
Kotvytska, Alina Anatolivna
Котвицька Аліна Анатоліївна
Tykhonovych, Kseniia Volodymyrivna
Тихонович Ксенія Володимирівна
Tsuber, ViktoriiaYuriivna \ed.\
Цубер Вікторія Юріївна

Примірників всього: 158
ЧЗ (1), Наук.Аб. (3), Гурт.4 (1), Уч.Аб. (149), ННА (4)
Вільні: ЧЗ (1), Наук.Аб. (3), Гурт.4 (1), Уч.Аб. (149), ННА (4)

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